Plique-à-jour is a vitreous enamelling technique where the enamel is applied in cells, similar to cloisonné, but with no backing in the final product, so light can shine through the transparent or translucent enamel. It is in effect a miniature version of stained-glass and is considered very challenging technically: high time consumption (up to 4 months per item), with a high failure rate. The technique is similar to that of cloisonné, but using a temporary backing that after firing is dissolved by acid or rubbed away. Reference: Wikipedia.
The technique was very suited to the Art Nouveau style and can be found on many different items from that era.
Below are some examples and price guides of Art Nouveau items using Plique-a-jour techniques including a dragonfly brooch and a Norwegian vase by Marius Hammer.